Dramatic enhancement of carrier mobility via effective secondary structural arrangement resulting from the substituents in a porphyrin transistor.

نویسندگان

  • Soojung Choi
  • Seung Hyun Chae
  • Jicheol Shin
  • Youngmee Kim
  • Sung-Jin Kim
  • Dong Hoon Choi
  • Suk Joong Lee
چکیده

OFET devices based on single-crystals of two different porphyrin derivatives display excellent mobilities of 2.57 and 0.48 cm(2) V(-1) s(-1). Although they generate similar J-aggregations, the dramatic enhancement of mobility obtained using porphyrin 1 is due to the well-confined secondary structural arrangement caused by substituents on the porphyrin ring.

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عنوان ژورنال:
  • Chemical communications

دوره 49 38  شماره 

صفحات  -

تاریخ انتشار 2013